Difatty acyl urea from corn oil: synthesis and characterization.

نویسندگان

  • Emad A Jaffar Al-Mulla
  • Wan Md Zin Wan Yunus
  • Nor Azowa Bt Ibrahim
  • Mohd Zaki A Rahman
چکیده

In this study, difatty acyl urea has been successfully synthesized from corn oil using sodium ethoxide as a catalyst. Ethyl fatty ester and glycerol were produced as by-products. In this reaction, corn oil was refluxed with urea in ethanol. The highest conversion percentage (78%) was obtained when the process was carried out for 8 hours using urea to corn oil ratio of 5.6: 1.0 at 78 degrees C. Both difatty acyl urea and ethyl fatty ester have been characterized using elemental analysis, Fourier transform infrared (FTIR) spectroscopy and (1)H nuclear magnetic resonance (NMR) technique.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Synthesis and characterization of N,N'-carbonyl difatty amides from palm oil.

N,N'-Carbonyl difatty amides (CDFAs) have been synthesized from palm oil using sodium ethoxide as catalyst. Ethyl fatty esters (EFEs) were produced as a by-product as well as glycerol. The synthesis was carried out by reflux palm oil and urea in presence of ethanol. In this process, palm oil gave 79% pure CDFAs after 8 hours and molar ratio of urea to palm oil was 6.2: 1 at 78 degrees C. Both C...

متن کامل

Synthesis, Characterization and Antibacterial Activity Studies of Some N-Acyl-N'-aryl Thiourea Derivatives

Some N¬-acyl-N'-aryl thiourea derivatives 4(a-f) have been prepared by the reaction of acyl halides ammonium thiocyanate and aryl amines. The structures of synthesized compounds have been characterized by IR, 1HNMR spectral studies. The synthesized compounds 5(a-f) have been screened for antibacterial activity. The effect of the structure of the investigated compounds on the antibacterial activ...

متن کامل

Evaluation of various extracted vegetable oils, roasted soybeans, medium-chain triglyceride and an animal-vegetable fat blend for postweaning swine.

A total of 280 crossbred pigs weaned at 21 d of age and weighing approximately 6 kg were utilized in five replicates to evaluate pig growth responses when fed a basal diet or one of several dietary lipid sources during a 4-wk postweaning period. A basal corn-soybean meal-corn starch-dried whey diet was compared with diets supplemented at a 7.75% level with one of the following lipid sources: co...

متن کامل

Factor Analysis of Seed Yield, Its Components and Oil Content of Corn Genotypes Affected Nitroxin Fertilizer

Fertilizer management is essential for achieving sustainable agriculture and protecting the environment. To evaluate the effect of Nitroxin bio-fertilizer application on quantitative and qualitative traits of corn hybrids a farm research was arranged via split plot experiment based on the randomized complete block design with four replications in 2013. Main plots were Included: use of the chemi...

متن کامل

Effects of D Ietary Dried Whey and Corn Oil on Weanling Pig Performance, Fat Digestibility and Nitrogen Util Ization 1,2

Two experiments were conducted to evaluate the effects and interactions of dietary levels of corn oil (0 vs 6%) and dried whey (0 vs 25%) on performance of young pigs during a4-wk postweaning period. The first experiment, conducted in five replicates as a 2 • 2 factorial in a randomized block design, evaluated gain and feed intakes of 172 pigs weaned at 21 d of age. Pigs were bled at weekly int...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Journal of oleo science

دوره 59 3  شماره 

صفحات  -

تاریخ انتشار 2010